3-Methyl­butyl 2-(5-iodo-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate

نویسندگان

  • Hong Dae Choi
  • Pil Ja Seo
  • Byeng Wha Son
  • Uk Lee
چکیده

In the title compound, C(15)H(17)IO(4)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The crystal structure is stabilized by weak inter-molecular C-H⋯π inter-actions between a methyl H atom of the methyl-sulfinyl group and the benzene ring of the benzofuran system, and by an I⋯O halogen bond of 3.173 (3) Å and a nearly linear C-I⋯O angle of 171.7 (1)°. In addition, the crystal structure exhibits weak inter-molecular C-H⋯O hydrogen bonds. The O atom of the carbonyl group and the butyl chain are both disordered over two positions with site-occupancy factors from refinement of 0.55 (4) and 0.45 (4) (for the O atom), and 0.76 (2) and 0.24 (2) (for the butyl group).

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009